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Assembly of polyamines via amino acids from three components using cobalt(III) template methodology

Lookup NU author(s): Dr Gilles Laval, Professor William Clegg, Emeritus Professor Bernard Golding

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Abstract

A versatile and efficient template synthesis has been developed to synthesise novel polyamines [e.g. rac-N3-(3-aminopropyl)butane-1,3-diamine, isospermidine 1] via amino acids [e.g. (2R,4S/2S,4R)-N4-(3-aminopropyl)-2,4-di-aminopentanoic acid] using cobalt(III) to assemble the three precursor components in a biomimetic manner.

Publication metadata

Author(s): Laval G, Clegg W, Crane CG, Hammershoi A, Sargeson AM, Golding BT

Publication type: Article

Publication status: Published

Journal: Chemical Communications

Year: 2002

Volume: 8

Issue: 17

Pages: 1874-1875

ISSN (print): 1359-7345

ISSN (electronic): 1364-548X

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/b206462f

DOI: 10.1039/b206462f

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