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Ruthenium-carbon bond formation via cyclometallation of a nucleobase

Lookup NU author(s): Clayton Price, Michelle Shipman, Sarah Gummerson, Professor Andrew HoultonORCiD, Professor William Clegg, Dr Mark Elsegood

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Abstract

The presence of a chelating tether attached to ethylguanine leads to the formation of a metal-carbon bond at C8 of the nucleobase when reacted with trans-[RuCl4(dmso)2]-, in contrast, more typical co-ordination at N7 is seen in the absence of the tether. © The Royal Society of Chemistry 2001.

Publication metadata

Author(s): Price C, Shipman MA, Gummerson SL, Houlton A, Clegg W, Elsegood MRJ

Publication type: Article

Publication status: Published

Journal: Journal of the Chemical Society, Dalton Transactions

Year: 2001

Issue: 4

Pages: 353-354

Print publication date: 01/01/2001

ISSN (print): 1472-7773

ISSN (electronic): 1364-5447

Publisher: Royal Society of Chemistry

URL: http://dx.doi.org/10.1039/b009766g

DOI: 10.1039/b009766g

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