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Substitution of Aromatic Oil with Palm Oil in Natural Rubber/Silica Composites via Latex Processing

Lookup NU author(s): Dr Kheng-Lim GohORCiD

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This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License (CC BY-NC-ND).


Abstract

© 2026 The Authors. Published by American Chemical Society. This article is licensed under CC-BY 4.0. https://creativecommons.org/licenses/by/4.0/ Rubber materials incorporating vegetable oils are being developed as sustainable alternatives to conventional petroleum-derived plasticizers. In this study, palm oil (PO) was used as a green processing oil for natural rubber (NR) composites, and aromatic oil (AO) was included for comparative analysis. The preparation of rubber material via the latex method, with and without vulcanizing agents, was also compared to the conventional preparation method. The test results showed that replacing AO with PO in the latex method yielded a similar cure rate index. The Payne effect, indicating the extent of filler–rubber interaction via the latex method, was 182 kPa for AO and 171 kPa for PO. The mechanical properties in terms of the Young’s modulus of the PO-based composites were higher than those of the AO-based counterparts. Furthermore, the PO-based composites exhibited the smallest tan δ value at 60 °C (0.05), indicating the lowest rolling resistance. Life cycle assessment results showed that the PO-based natural rubber latex reduces fossil fuel depletion, human toxicity, and ozone layer depletion. Moreover, the latex method reduces human toxicity compared to the conventional method. Substituting PO in place of AO in rubber compounds serves as a suitable alternative plasticizer for rubber products.


Publication metadata

Author(s): Yangthong H, Udomsin P, Lim-arun P, Suethao S, Kaewpradit P, Jittham P, Sucharitpwatskul S, Mougin K, Spangenberg A, Le Duigou A, Goh KL, Smitthipong W

Publication type: Article

Publication status: Published

Journal: ACS Omega

Year: 2026

Volume: 11

Issue: 24

Pages: 35913-35927

Print publication date: 23/06/2026

Online publication date: 11/06/2026

Acceptance date: 09/06/2026

Date deposited: 06/07/2026

ISSN (electronic): 2470-1343

Publisher: American Chemical Society

URL: https://doi.org/10.1021/acsomega.6c02667

DOI: 10.1021/acsomega.6c02667


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Funding

Funder referenceFunder name
Franco-Thai Cooperation Programme in Higher Education and Research (Franco-Thai Mobility Programme/PHC SIAM) Year 2024–2025

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