Toggle Main Menu Toggle Search

Open Access padlockePrints

The Newcastle University research output collection, currently available on ePrints, will shortly be moving to a new open repository platform, Figshare. To prepare for the data migration we have paused adding new content to ePrints, and will resume once the new repository is launched. During this time you will continue to have access to ePrints (but no new content will appear). We will share updates here when available.

Lithium, sodium and potassium enolate aggregates and monomers: syntheses and structures

Lookup NU author(s): Dr Nathan Davison, Dr Jack Hemingway, Dr Paul Waddell, Dr Erli Lu

Downloads

Licence

This work is licensed under a Creative Commons Attribution 4.0 International License (CC BY 4.0).

Abstract

© 2024 The Royal Society of Chemistry. In this Article, we report the syntheses and comparative structural studies of lithium, sodium, and potassium anthracen-9-yl enolates, as their aggregates (Li, Na: hexamer; K: tetramer) and ligand-stabilized monomers (for Li and Na). The monomers add new members to the rare collection of group-1 metal monomeric enolates. Moreover, the series covers different group-1 metal cations (Li+, Na+ and K+) and aggregate sizes, allowing comparative structural studies to elucidate how the metal identity and aggregate size influence the enolate structure.

Publication metadata

Author(s): Davison N, Hemingway JM, Waddell PG, Lu E

Publication type: Article

Publication status: Published

Journal: Dalton Transactions

Year: 2024

Volume: 53

Pages: 4719-4728

Online publication date: 12/02/2024

Acceptance date: 09/02/2024

Date deposited: 05/03/2024

ISSN (print): 1477-9226

ISSN (electronic): 1477-9234

Publisher: Royal Society of Chemistry

URL: https://doi.org/10.1039/d4dt00211c

DOI: 10.1039/d4dt00211c

Altmetrics

Altmetrics provided by Altmetric

Funding

Funder referenceFunder name
Leverhulme Trust
Newcastle University Academic Track (NUAcT) Fellowship
RPG-2022-231

Share