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Melaminium Lanthanide Oxalate Coordination Compounds –Synthesis and Structural Varieties

Lookup NU author(s): Dr Liana Vella-Zarb, Dr Ulrich Baisch

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Abstract

© 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim A crystal engineering approach affords novel crystalline ionic coordination networks occurring in two different compositions. [C3H7N6]6[Ln(C2O4)4][NO3] (1) (Ln = Dy, Ho), which is isostructural to its ytterbium homologue and [C3H7N6][Ln(C2O4)2(H2O)] (2) (Ln = Ce, Gd). The crystal structure of 1 is based on the interaction between isolated monomeric building-blocks of [Ln(C2O4)4]5– and melaminium cations. The melaminium cations form parallel layers, in which the lanthanide oxalato anion is intercalated. On the other hand, 2 consists of a 2D framework of interconnected lanthanide oxalate units with isolated melaminium cations intercalated between the metal complex layers.

Publication metadata

Author(s): Vella-Zarb L, Baisch U

Publication type: Article

Publication status: Published

Journal: Zeitschrift fur Anorganische und Allgemeine Chemie

Year: 2017

Volume: 643

Issue: 21

Pages: 1712-1716

Print publication date: 17/11/2017

Online publication date: 06/11/2017

Acceptance date: 02/04/2016

ISSN (print): 0044-2313

ISSN (electronic): 1521-3749

Publisher: Wiley-VCH Verlag

URL: https://doi.org/10.1002/zaac.201700299

DOI: 10.1002/zaac.201700299

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