Toggle Main Menu Toggle Search

Open Access padlockePrints

The Newcastle University research output collection, currently available on ePrints, will shortly be moving to a new open repository platform, Figshare. To prepare for the data migration we have paused adding new content to ePrints, and will resume once the new repository is launched. During this time you will continue to have access to ePrints (but no new content will appear). We will share updates here when available.

Impact of a rigid backbone on the structure of an agostically-stabilised dialkylstannylene: isolation of an unusual bridged stannyl–stannylene

Lookup NU author(s): Dr Keith IzodORCiD, Dr Casey Dixon, Dr Ross Harrington, Professor Mike ProbertORCiD

Downloads

Licence

This work is licensed under a Creative Commons Attribution 4.0 International License (CC BY 4.0).

Abstract

The reaction between the phosphine–borane-stabilised dicarbanioncomplex [1,2-C6H4{CHP(BH3)Cy2}2][Li(THF)n]2 and Cp2Sn gives theunusual stannyl–stannylene [[1,2-C6H4{CHP(BH3)Cy2}2]Sn]21/2PhMe, in which one dicarbanion ligand chelates a tin centre, while theother bridges a tin–tin bond. The stannylene centre is stabilised byan agostic-type B–H  Sn interaction.

Publication metadata

Author(s): Izod K, Dixon CM, Harrington RW, Probert MR

Publication type: Article

Publication status: Published

Journal: Chemical Communications

Year: 2015

Volume: 51

Issue: 4

Pages: 679-681

Online publication date: 21/11/2014

Acceptance date: 14/11/2014

Date deposited: 15/12/2014

ISSN (print): 1359-7345

ISSN (electronic): 1364-548X

Publisher: R S C Publications

URL: http://dx.doi.org/10.1039/c4cc08740b

DOI: 10.1039/c4cc08740b

Altmetrics

Altmetrics provided by Altmetric

Share