Toggle Main Menu Toggle Search

Open Access padlockePrints

The Newcastle University research output collection, currently available on ePrints, will shortly be moving to a new open repository platform, Figshare. To prepare for the data migration we have paused adding new content to ePrints, and will resume once the new repository is launched. During this time you will continue to have access to ePrints (but no new content will appear). We will share updates here when available.

Efficient Multigram Syntheses of Air-Stable, Chiral Primary Phosphine Ligand Precursors via Palladium-Catalyzed Phosphonylation of Aryltriflates

Lookup NU author(s): Arne Ficks, Connor Sibbald, Dr Ross Harrington, Professor William Clegg, Dr Lee HighamORCiD

Downloads

Full text for this publication is not currently held within this repository. Alternative links are provided below where available.

Abstract

Air-stable, chiral primary phosphines have been synthesized on a multigram scale. The key synthetic step is an optimized palladium-catalyzed phosphonylation reaction of aryltriflates, which opens up a valuable synthetic route to a chiral scaffold that is easily derivatized into novel phosphines.

Publication metadata

Author(s): Ficks A, Sibbald C, Ojo S, Harrington RW, Clegg W, Higham LJ

Publication type: Article

Publication status: Published

Journal: Synthesis

Year: 2013

Volume: 45

Issue: 2

Pages: 265-271

Print publication date: 01/01/2013

ISSN (print): 0039-7881

ISSN (electronic): 1437-210X

Publisher: Georg Thieme Verlag

URL: http://dx.doi.org/10.1055/s-0032-1316825

DOI: 10.1055/s-0032-1316825

Altmetrics

Altmetrics provided by Altmetric

Share